[update: Tyler Robinson has replied in comments — Tim /update]
Talkshop contributor ‘Cementafriend’ has emailed me with an interesting critique of parts the 2013 Robinson & Catling paper Common 0.1 bar tropopause in thick atmospheres set by pressure-dependent infrared transparency
. He is an engineer and tells me that:
I have had actual experience with combustion and heat transfer. I have designed burners for coal, gas, oil and waste fuel materials. I have measured CO2 in exhaust gases, down coal mines and even in the atmosphere.
The presence of OH in the atmosphere is due to the reaction CH4 +O3 > CH3OH +O2 (of course other organics can also be oxidised by O3 but the quantity of these is tiny).
The reaction claimed CH4 +OH> CH3 +H2O is not correct. CH3OH (methanol or methyl alcohol sometimes known as wood alcohol which is poisonous) can exist as a molecule. In water this can form the ions CH3+ and OH-.
CH3OH is highly soluble in water at ocean/lake surfaces and also in drops of water in clouds. However, there is little O3 in the atmosphere up to 11,000 km and that is why CH4 persists in the atmosphere now at around 1.7 ppm.
It seems that just as there are “Climate Scientists” making up false relations in physics, thermodynamics & heat transfer (luckily they have not touched mass transfer), there also seem to be “astrophysicists” and “astrochemists” making up new chemistry & reaction kinetics.